Yo, New Smoker, you sure know how to open a can of worms! The amount of quality VaPers out there is staggering... that is why you should start at the top, and work your way down. I have recently traveled down this road, this road being the exploration of VaPers, and have a few thoughts:
Start with Escudo, period, end of sentence. This is almost unequivocally (as far as that word can be used amongst those who play with pipes and tobaccos!) the KING of VaPers. Then, move to, oh, I don't know.... Solani 633 or maybe GLP Filmore, both considered shining examples of the genre. Then, start branching out.
According to Kilted 1, and many others, do not miss GLP's Haddo's Delight. I have been meaning to try this one! Also, Cornell and Diehl have many excellent VaPers, check out Kajun Kake, Bayou Morning, Three Friars, and Exhausted Rooster.
In my opinion, start with the classics (Escudo, Solani 633, and Filmore) and work your way out from there. PS Luxury Bullseye Flake is very highly regarded, and if you like that, you should have a blast checking out all the VaPer blends out there... Have fun, and happy hunting!